Bright Side of Lignin Depolymerization: Toward New Platform Chemicals
نویسندگان
چکیده
منابع مشابه
Bright Side of Lignin Depolymerization: Toward New Platform Chemicals
Lignin, a major component of lignocellulose, is the largest source of aromatic building blocks on the planet and harbors great potential to serve as starting material for the production of biobased products. Despite the initial challenges associated with the robust and irregular structure of lignin, the valorization of this intriguing aromatic biopolymer has come a long way: recently, many crea...
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Lignin is a recalcitrant and underexploited natural feedstock for aromatic commodity chemicals, and its degradation generally requires the use of high temperatures and harsh reaction conditions. Herein we present an ambient temperature one-pot process for the controlled oxidation and depolymerization of this potent resource. Harnessing the potential of electrocatalytic oxidation in conjugation ...
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Depolymerization of lignin in wood with hydrogen iodide in a nonpolar solvent is a selective, high-yield reaction that releases a diiodide of potential synthetic value into the solution. Finely milled wood (Douglas-fir, spruce, aspen, and sugarcane), was suspended in CDCl3 and treated with dry hydrogen iodide in a NMR tube. The yields and composition of the chloroform-soluble monomeric lignin d...
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Lignin is an integral part of the plant cell wall, which provides rigidity to plants, also contributes to the recalcitrance of the lignocellulosic biomass to biochemical and biological deconstruction. Lignin is a promising renewable feedstock for aromatic chemicals; however, an efficient and economic lignin depolymerization method needs to be developed to enable the conversion. In this study, w...
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ژورنال
عنوان ژورنال: Chemical Reviews
سال: 2018
ISSN: 0009-2665,1520-6890
DOI: 10.1021/acs.chemrev.7b00588